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Tuesday, February 10, 2009

Ion Exchange Membranes: Preparation, Characterization, Modification, and Application

Ion Exchange Membranes: Preparation, Characterization, Modification, and Application.
By Toshikatsu Sata
  • Publisher: Royal Society of Chemistry
  • Number Of Pages: 314
  • Publication Date: 2004-07-13
  • ISBN-10 / ASIN: 0854045902
  • ISBN-13 / EAN: 9780854045907
Product Description:

Various separation membranes have been developed since their discovery over half a century ago, providing numerous benefits and fulfilling many applications in our everyday lives. They lend themselves to techniques ranging from microfiltration and gas separation, to what can be considered as the most advanced technique - ion exchange.

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Advanced pH Measurement and Control, 3rd Edition

Advanced pH Measurement and Control, 3rd Edition.
By Gregory K. McMillan, Robert A. Cameron
  • Publisher: ISA
  • Number Of Pages: 294
  • Publication Date: 2004-10-30
  • ISBN-10 / ASIN: 1934394432
  • ISBN-13 / EAN: 9781934394434
Product Description:

This best-selling book is now expanded and updated, providing a clear, concise, and comprehensive view of how to select, install, and maintain electrodes, control valves, and control strategies for pH applications critical for product and water quality in the process industry. The book covers every aspect of system design including the mixing and reagent piping requirements that are important for a successful application. The essential concepts are summarized as key insights and the best practices are presented as rules of thumb throughout the book. The emerging capability of dynamic online pH estimators is explored to make existing pH measurements faster and more reliable. The latest developments in advanced batch control, adaptive control, linear reagent demand control, and model predictive control are presented to reduce reagent consumption and variability. A Microsoft Excel workbook file is included that lets users generate titration curves and analyze pH control system performance. A virtual plant is also offered to prototype and study pH control systems. The dynamic process models and control system modules for the virtual plant require the use of DeltaV SimulatePro and HYSYS Plant licenses.

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Liquid Phase Oxidation, Volume 16 (Comprehensive Chemical Kinetics)

Liquid Phase Oxidation, Volume 16 (Comprehensive Chemical Kinetics).
By R.G. Compton, C.H. Bamford, C.F.H. Tipper†
  • Publisher: Elsevier Science
  • Number Of Pages: 264
  • Publication Date: 1980-08-15
  • ISBN-10 / ASIN: 0444418601
  • ISBN-13 / EAN: 978044441860
Section 6 deals with the autocatalytic reactions of inorganic and organic
compounds with molecular oxygen in the liquid phase and the highly exothermic
processes in the gas phase, collectively known as combustion,
which may involve oxygen, other oxidants or decomposition flames and
are so important technologically. Catalysis, retardation and inhibition are
covered. The kinetic parameters of the elementary steps involved are
given, when available, and the reliability of the data discussed.
Volume 16 covers oxidation in the liquid phase by ground state and
singlet molecular oxygen, and by ozone. The free-radical chain mechanisms
involved and the complex role of hydroperoxides, dihydroperoxides,
peroxides and polyoxides, together with the mechanism of the action of
catalysts and inhibitors (in particular metal salts, amines and phenols) are
discussed in detail. The important role of hydrogen bonding is considered.
Chapter 1 deals with the oxidation of alkanes, aralkanes and olefins,
Chapter 2 with the oxidation of saturated and unsaturated aliphatic aldehydes
and aromatic aldehydes, Chapter 3 with the oxidation of alcohols,
ketones, ethers, carboxylic acids, esters and phenols, and Chapter 4 with
the oxidation of organic compounds of nitrogen (mainly amines), sulphur
(sulphides, thiols and the reactions of the sulphoxide products) and
chlorine. Cooxidation of various organic reactants, e.g. hydrocarbons and
alcohols, is also discussed.
Liverpool
December 1 9 79
C.H. Bamford
C.F.H. Tipper

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Chemical Methods in Gas Chromatography (Journal of Chromatography Library) Volume 24

Chemical Methods in Gas Chromatography (Journal of Chromatography Library)
By V. G. Berezkin
  • Publisher: Elsevier Science&Technology
  • Number Of Pages: 313
  • Publication Date: 1983-10
  • ISBN-10 / ASIN: 0444419519
  • ISBN-13 / EAN: 9780444419514
Introduction
The advances made in science and technology in the second half of the twentieth
century are closely associated with the development of analytical methods. ‘Science
progresses in quantum leaps depending on the advances in methods. Every forward step
in the development of methods brings us to a new height from which we observe a
broader vista with previously unseen objects’ - such was the vivid and accurate assessment
of the significance of new methods by Pavlov.
One of the most significant and spectacular achievements in analytical chemistry
over the past quarter of a century has been the development and wide practical application
of gas chromatography (GC). GC marked dramatic progress in the studying of
complex mixtures of organic compounds and inorganic gases.
The application of GC in chemical analysis has substantially advanced many branches
of analytical chemistry and brought forth radical changes in the organic analysis of
volatile compounds. Many determinations that had been practically impossible or
demanded several days of arduous work have become accessible to any investigator
in an ordinary laboratory with the aid of GC.
GC was a gigantic leap forward in studies of complex mixtures of organic compounds
and inorganic gases. A tremendous improvement has been achieved in such basic characteristics
of analytical experiments as sensitivity (detection limit), selectivity (resolving
power), accuracy, speed and reliability.
The extensive use of GC in science and industry has given rise to a large volume of
literature. Fig. 1 shows diagramatically the distribution of publications on individual
analytical methods in the analysis of organic compounds and gases [ l ] . It can be seen
that in 1975 45% of all publications on the analytical chemistry of organic compounds
and gases dealt with chromatographic methods, GC accounting for 26% of the total
number of works on chromatography. Table 1 lists analytical methods in decreasing
order of their frequency of use by subscribers to Analytical Chemistry [ 2 ] . The table
demonstrates that GC is currently one of the most widely used techniques. Another
indication of the wide popularity of GC is the volume of production of gas chromatographs.
For example, in the U.S.A. alone one (American) billion dollars worth of chromatographs
are produced each year and 47.9% of all research laboratories in that country
use GC [3].
The development of GC methods and the extension of areas of their application are
continuing even today, with emphasis on combined or, to use Zolotov’s definition, hybrid
methods [4] incorporating two and more techniques. The promising nature of the
combined use of several chemical methods has been pointed out by Ostwald, who wrote
that, if separation cannot be achieved directly by physical methods, one has the alternative
of providing the right conditions for the isolation of a new phase by appropriately
transforming the separated substances and other compounds, the new phase containing a
derivative of the sample substance and enabling its mechanical separation [5]. The
attractive idea of combining chemical and physical methods was later elaborated.

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Principles and Practices of Method Validation Proceedings (Special Publication).

Principles and Practices of Method Validation Proceedings (Special Publication).
By A. Fajgelj, A. Ambrus
  • Publisher: Royal Society of Chemistry
  • Number Of Pages: 305
  • Publication Date: 2000-11-03
  • ISBN-10 / ASIN: 0854047832
  • ISBN-13 / EAN: 9780854047833
Product Description:

Principles and Practices of Method Validation is an overview of the most recent approaches used for method validation in cases when a large number of analytes are determined from a single aliquot and where a larege number of samples are to be analysed. Much of the content relates to the validation of new methods for pesticide residue analysis in foodstuffs and water but the principles can be applied to other similar fields of analysis. Different chromatographic methods are discussed, including estimation of various effects, eg. matrix-induced effects and the influence of the equipment set-up. The methods used for routine purposes and the validation of analytical data in the research and development environment are documented. The legislation covering the EU-Guidance on residue analytical methods, an extensive review of the existing in-house method validation documentation and guidelines for single-laboratory validation of analytical methods for trace-level concentrations of organic chemicals are also included. With contributions from experts in the field, any practising analyst dealing with method validation will find the examples presented in this book a useful source of technical information

Practical Guide to Polyvinyl Chloride

Practical Guide to Polyvinyl Chloride.
By Stuart Patrick
  • Publisher: Smithers Rapra Press
  • Number Of Pages: 170
  • Publication Date: 2008-04-22
  • ISBN-10 / ASIN: 1859575110
  • ISBN-13 / EAN: 9781859575116
Product Description:

Polyvinyl chloride (PVC) has been around since the late part of the 19th century, although it was not produced commercially until the 1920s; it is the second largest consumed plastic material after polyethylene. PVC products can be rigid or flexible, opaque or transparent, coloured, and insulating or conducting. There is not just one PVC but a whole family of products tailor-made to suit the needs of each application.

Rapra's Practical Guide to PVC is packed with information for everyone working with PVC. It provides comprehensive background on the resins and additives, their properties and processing characteristics, as well as discussion of product design and development issues.

PVC is extremely cost effective in comparison to other plastics with a high degree of versatility in end-use and processing possibilities, as the reader will note from this book. It is durable, easily maintained, and can be produced in a large range of colours. As a result PVC finds use in an extensive range of applications in virtually all areas of human activity, including medical equipment, construction applications such as flexible roof membranes, pipes and window profiles, toys, automotive parts and electrical cabling.

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Practical Guide to Polyimides

Practical Guide to Polyimides.
By Alexander L Rusanov, Marc JM Abadie
  • Publisher: Smithers Rapra Press
  • Number Of Pages: 88
  • Publication Date: 2007-08-13
  • ISBN-10 / ASIN: 1847350585
  • ISBN-13 / EAN: 9781847350589
Product Description:

Polyimides are very durable, easy to machine and have exceptional heat and chemical resistance. They are also highly insulative and do not contaminate their surroundings. Their strength and heat and chemical resistance are so great that they are often used to replace glass and metals, such as steel, in many demanding industrial applications. Polyimides are even used in many everyday applications. They are used in cars both externally and internally because they can withstand the intense heat and the corrosive lubricants, fuels, and coolants found in cars. They are also used in the construction of many appliances as well as microwave cookware and food packaging because of their thermal stability, resistance to oils, greases, and fats and their transparency to microwave radiation. They can also be used in circuit boards, insulation, fibres for protective clothing, composites, and adhesives. This report covers the synthesis of polyimides from chloral and trinitrotoluene and reviews the production of new types of polyimides combining good thermal, mechanical and electrical properties with improved processability. It is ideal for those who work with polyimides, either producing them or those using them to manufacture other goods. It will be of interest to those in both academia and industry.

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Analytical Measurement Terminology: Handbook of Terms Used in Quality Assurance of Analytical Measurement

by: Elizabeth Prichard
en | Royal Society of Chemistry | 2001-11-09

0854044434 9780854044436.

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Sunday, February 8, 2009

Domino Reactions in Organic Synthesis

Domino Reactions in Organic Synthesis.

Lutz F. Tietze, Hubertus P. Bell, Gordon Brasche

Publisher: Wiley-VCH
Number Of Pages: 631
Publication Date: 2006-10-27

Book Description:

Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates—a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type—an approach for an efficiant, economically benificial and ecological benign synthesis definite must for every organic chemist.

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http://rapidshare.com/files/18489796/DROS.rar.html
http://mihd.net/w6nx59

Enantiomer Separation: Fundamentals and Practical Methods

Enantiomer Separation: Fundamentals and Practical Methods.

Fumio Toda

Publisher: Springer
Number Of Pages: 336
Publication Date: 2005-04-19

Descreption
Enantiomer Separation is written by several experts working in modern enantiomer separation chemistry who understand the needs of the many scientific and engineering chemists who need a cost-efficient supply of optically active materials of high quality. This book contains the following modern practical methods of enantiomer separation: Inclusion complexation of a racemic compound with a chiral host compound, which gives chiral host-chiral guest inclusion compounds, from which the chiral guest can be obtained. When this separation is combined with distillation technique, for example, enantiomer separation can be accomplished by fractional distillation in the presence of a chiral host compound. This is a modern and "green" procedure of enantiomer separation. These separation methods are described in several chapters of the book. Biological separation methods and "green" methods are covered in two chapters. Enantiomer separation by chromatography on a column containing chiral solid phase is one of the most up-to-date and well known "green" methods of enantiomer separation. Two experts in chromatography have contributed to provide two very important chapters on this method of separation. Practical methods of enantiomer separation are important both in the research laboratory and in industry, especially in the pharmaceutical, fine chemical and electronic industries. Chemists and engineers, as well as students who are working in the field of chiral compounds in universities, institute and industry, will find this book an invaluable resource.
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Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis

Quaternary Stereocenters: Challenges and Solutions for Organic Synthesis.
Steven V. Ley, Jens Christoffers, Angelika Baro

Publisher: Wiley-VCH
Number Of Pages: 359
Publication Date: 2006-01-09

Filling the gap in the literature, this book presents everything there is to know about this topic. By comprehensively covering the quaternary stereocenters found in a range of important and useful molecules in pharmaceutical and medicinal applications, as well as in thousands of natural products, the book provides the know-how chemists need to synthesize challenging molecules with numerous applications.
A must for organic chemists in academia, the pharmaceutical industry and medicine.
From the Contents:
Important Natural Products
Important Pharmaceuticals and Intermediates
Aldol Reactions
Michael Reactions and Conjugate Additions
Cycloaddition Reactions
Rearrangement Reactions
Alkylation of Ketones and Imines
Asymmetric Allylic Alkylation
Asymmetric Cross Coupling and Heck Reactions
Phase Transfer Catalysis
Enzymatic Methods
Radical Reactions

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Handbook of Hydroxyacetophenones

Handbook of Hydroxyacetophenones.
R. Martin
Publisher: Springer
Number Of Pages: 548
Publication Date: 1997-05-31

Description:
Hydroxyacetophenones constitute the starting material for a wide variety of syntheses in organic chemistry. They are versatile building serving many different applications, such as specialty polymers, pharmaceuticals and fine chemicals. In this Handbook the diverse ways of obtaining over 3000 hydroxyacetophenones are described and their physico-chemical properties and spectroscopic data references are indicated. The Handbook is presented in dictionary style, with a logical classification of the ketones, making the information easily available for consultation. Ketones are classified methodically. They are thus easily accessible from three tables: - the molecular formula index - the chemical abstracts registry - the usual names index. This completely revised and enlarged edition includes:- 10 additional chapters compared with the previous edition which had just 2 chapters - an additional 1500 ketones - updated information for ~1200 ketone entries - the addition of di- and polyketones - approximately 3500 references. This Handbook is the reference on hydroxyacetophenones. It is a powerful synthesis tool for the researcher or industrial producers. Nowhere else are so many compounds covered or the physical properties and relevant syntheses provided. It provides a wide choice of hydroxyketones required to achieve syntheses based upon this range of intermediates.

http://mihd.net/ie8w2pz/__3828b02__.html

Organic Light-Emitting Devices: A Survey

Organic Light-Emitting Devices: A Survey.
Joseph Shinar
Publisher: Springer
Number Of Pages: 309
Publication Date: 2003-10-31

Description:
Although it has long been possible to make organic materials emit light, it has only recently become possible to do so at the level and with the efficiency and control necessary to make the materials a useful basis for illumination or displays. The early electroluminescent devices provided reasonably bright light, but required high operating voltages, produced only a narrow range of colors, and had severely limited lifetimes. Recent developments, however, make it possible to manufacture organic light-emitting devices that are thin, bright, efficient, and stable and that produce a broad range of colors. This book surveys the current status of the field. It begins with an overview of the physics and chemistry of organic light emitting devices by J. Shinar and V. Savvateev. Subsequenbt chapters discuss the design of molecular materials for high performance devices (C. Adachi and T. Tsutsui) and chemical degradation and physical aging (K. Higginson, D. L. Thomsen, B. Yang, and F. Papadimitrakopoulos). A. Dodabalapur describes microcavity OLEDs, and Y. Shi, J. Liu, and Y. Yang discuss polymer morphology and device performance. Various aspects of devices based on polyparaphenylene vinylenes are discussed in chapters by N.C. Greenham and R.H. Friend and by H. Chayet, V. Savvateeyv, D. Davidov and R. Neumann. Chapters by S. Tasch, W. Graupner, and G. Leising and by Y. Z. Wang, D. Gebler, and A. J. Epstein describe OLEDs based on poly(paraphenylene) and poly(pyridine), respectively. The book concludes with a chapter on polyfluorene-based devices, which show great promise for producing light in all colors from blue to red.

http://mihd.net/xn8ih73

Azaheterocycles Based on a,ß-Unsaturated Carbonyls By Valentin A. Chebanov, Sergey M. Desenko, Thomas W. Gurley

Azaheterocycles Based on a,ß-Unsaturated Carbonyls By Valentin A. Chebanov, Sergey M. Desenko, Thomas W. Gurley.
Publisher: Springer
Number Of Pages: 210
Publication Date: 2008-11-01
ISBN-10 / ASIN: 3540683615
ISBN-13 / EAN: 9783540683612
Binding: Hardcover

Product Description:

This monograph is devoted to heterocyclization of aliphatic and aromatic a,ß-unsaturated carbonyls with various binucleophiles. These reactions produce partially hydrogenated nitrogen-containing heterocycles that are interesting due to their significant role in biological processes. They can be used in conjunction with combinatorial high throughput methods that involve microwave-assisted and ultrasonic-promoted reactions. The monograph is a comprehensive review of the known literature data devoted to the reactions of a,ß-unsaturated ketones, their synthetic equivalents and precursor. It is intended for chemists working in the field of experimental syntheses and theoretical investigations of nitrogen-containing heterocycles, lecturers at university and graduate student

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Handbook of Reagents for Organic Synthesis, Chiral Reagents for Asymmetric Synthesis

Handbook of Reagents for Organic Synthesis, Chiral Reagents for Asymmetric Synthesis .
Leo A. Paquette

Publisher: Wiley
Number Of Pages: 582
Publication Date: 2003-08-15

Description:
Derived from the renowned, Encyclopedia of Reagents for Organic Synthesis (EROS), the related editors have created a new handbook which focuses on chiral reagents used in asymmetric synthesis and is designed for the chemist at the bench This new handbook follows the same format as theEncyclopedia , including an introduction and an alphabetical arrangement of the reagents.
As chiral reagents are the key for the successful asymmetric synthesis, choosing the right reagents is essential, in this handy reference the editors give details on how to prepare, store and use the reagents as well as providing key reactions to demonstrate where reagents have been successfully used.

Activating Agents and Protecting Groups, Handbook of Reagents

Activating Agents and Protecting Groups, Handbook of Reagents
for Organic Synthesis.

by
Anthony J. Pearson, William R. Roush

By
Publisher: Wiley
Number Of Pages: 528
Publication Date: 1999-06-22
ISBN-10 / ASIN: 0471979279
ISBN-13 / EAN: 9780471979272
Binding: Hardcover

Product Description

Recognising the need for a cost effective reference work that deals not only with the most popular reagents in synthesis but also reaches the widest possible audience of practising organic chemists, the editors of 'The Encyclopedia of Reagents for Organic Synthesis' (EROS) have developed a list of the most important and useful reagents employed in the field, conveniently presented in four separate volumes.


The reagents included in this volume reflect the fact that protecting groups and activation procedures are often used in combination. There are many instances in the synthesis of natural and unnatural products, pharmaceuticals, oligosaccharides, and oligonucleotides, etc., where similar tactics must be employed to prevent undesired activation or reaction of functionality. Accordingly, the most important reagents used to protect amines, alcohols, carboxyl, carbonyl and other reactive functional groups are included in this volume. The list of activating agents includes well known reagents that activate functional groups for substitution or elimination reactions, as well as less traditional examples, e.g. HMPA used to "activate" enolates and alkyllithium reagents to increase the nucleophilicity.


Each article contains all of the information found in EROS as well as expanded related reagents listings and additional references to enable the reader to quickly access a broad range of information that is beyond the scope of the reagent entries themselves. This text will prove an invaluable resource
Link
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Analysis of Cosmetic Products

Analysis of Cosmetic Products.
advises the reader from an analytical chemistry perspective on the choice of suitable analytical methods for production monitoring and quality control of cosmetic products. In the format of an easy-to-understand compendium of published literature on the subject, this book will enable people working in the cosmetic industry or in research laboratories to:
* become familiar with the main legislative and analytical literature on this subject and
* learn about and choose suitable analytical procedures for production monitoring and control of cosmetic products, according to their composition.

The first section of Analysis of Cosmetic Products covers various definitions and concepts relating to cosmetic products, current legislation in different countries and specific legislation on ingredients. The central body of the book addresses analytical methods for monitoring and quality control of cosmetic products with the fundamental objective being to enable reader's access to scientific reviews carried out by experts in analytical chemistry. The final section contains a small review of the alternative methods to using animals for cosmetic product evaluation.
* An essential resource for those in the cosmetic industry and research laboratories, allowing you to become familiar with the main analytical literature
* Up-to-date and exhaustive overviews of current knowledge dealing with cosmetic analysis, general concepts and legislation
* Including tables and figures, designed to graphically communicate important information in an easy-to-understand format.

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Organic Spectroscopic Analysis (Tutorial Chemistry Texts)

Organic Spectroscopic Analysis (Tutorial Chemistry Texts).
By R.J. Anderson, D. Bendell, P W. Groundwater
  • Publisher: Royal Society of Chemistry
  • Number Of Pages: 192
  • Publication Date: 2004-04-28
  • ISBN-10 / ASIN: 0854044760
  • ISBN-13 / EAN: 9780854044764

Analytical Ultracentrifugation : Techniques and Methods

Analytical Ultracentrifugation : Techniques and Methods.
By et al D. Scott (Editor)

  • Publisher: Royal Society of Chemistry
  • Number Of Pages: 580
  • Publication Date: 2006-03-27
  • ISBN-10 / ASIN: 0854045473
  • ISBN-13 / EAN: 9780854045471
Product Description:

Analytical Ultracentrifugation has become an increasingly important technique for monitoring the size and shape of biological macromolecules. "Analytical Ultracentrifugation: Techniques and Methods" contains contributions from experts in the field, bringing together the multitude of developments that have taken place in instrumentation and analysis over the past decade into a single volume. This book covers the latest methods in analysis along with an extensive introduction for the novice user. Analysis methods in both sedimentation velocity and sedimentation equilibrium are discussed at length. Protein, Protein/DNA, membrane proteins and polymer systems are also explored, along with software developments and non-ideality.

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Developing Solid Oral Dosage Forms: Pharmaceutical Theory&Practice

Developing Solid Oral Dosage Forms: Pharmaceutical Theory&Practice.
By Yihong Qiu, Yisheng Chen, Geoff G.Z. Zhang, Lirong Liu, William Porter

  • Publisher: Academic Press
  • Number Of Pages: 950
  • Publication Date: 2008-12-15
  • ISBN-10 / ASIN: 0444532420
  • ISBN-13 / EAN: 9780444532428

Product Description:

This book is intended for pharmaceutical professionals engaged in research and development of oral dosage forms. It covers essential principles of physical pharmacy, biopharmaceutics and industrial pharmacy as well as various aspects of state-of-the-art techniques and approaches in pharmaceutical sciences and technologies along with examples and/or case studies in product development. The objective of this book is to offer updated (or current) knowledge and skills required for rational oral product design and development. The specific goals are to provide readers with:

Basics of modern theories of physical pharmacy, biopharmaceutics and industrial pharmacy and their applications throughout the entire process of research and development of oral dosage forms

Tools and approaches of preformulation investigation, formulation/process design, characterization and scale-up in pharmaceutical sciences and technologies

New developments, challenges, trends, opportunities, intellectual property issues and regulations in solid product development

The first book (ever) that provides comprehensive and in-depth coverage of what's required for developing high quality pharmaceutical products to meet international standards

It covers a broad scope of topics that encompass the entire spectrum of solid dosage form development for the global market, including the most updated science and technologies, practice, applications, regulation, intellectual property protection and new development trends with case studies in every chapter

A strong team of more than 50 well-established authors/co-authors of diverse background, knowledge, skills and experience from industry, academia and regulatory agencies.

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