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Tuesday, February 10, 2009

Liquid Phase Oxidation, Volume 16 (Comprehensive Chemical Kinetics)

Liquid Phase Oxidation, Volume 16 (Comprehensive Chemical Kinetics).
By R.G. Compton, C.H. Bamford, C.F.H. Tipper†
  • Publisher: Elsevier Science
  • Number Of Pages: 264
  • Publication Date: 1980-08-15
  • ISBN-10 / ASIN: 0444418601
  • ISBN-13 / EAN: 978044441860
Section 6 deals with the autocatalytic reactions of inorganic and organic
compounds with molecular oxygen in the liquid phase and the highly exothermic
processes in the gas phase, collectively known as combustion,
which may involve oxygen, other oxidants or decomposition flames and
are so important technologically. Catalysis, retardation and inhibition are
covered. The kinetic parameters of the elementary steps involved are
given, when available, and the reliability of the data discussed.
Volume 16 covers oxidation in the liquid phase by ground state and
singlet molecular oxygen, and by ozone. The free-radical chain mechanisms
involved and the complex role of hydroperoxides, dihydroperoxides,
peroxides and polyoxides, together with the mechanism of the action of
catalysts and inhibitors (in particular metal salts, amines and phenols) are
discussed in detail. The important role of hydrogen bonding is considered.
Chapter 1 deals with the oxidation of alkanes, aralkanes and olefins,
Chapter 2 with the oxidation of saturated and unsaturated aliphatic aldehydes
and aromatic aldehydes, Chapter 3 with the oxidation of alcohols,
ketones, ethers, carboxylic acids, esters and phenols, and Chapter 4 with
the oxidation of organic compounds of nitrogen (mainly amines), sulphur
(sulphides, thiols and the reactions of the sulphoxide products) and
chlorine. Cooxidation of various organic reactants, e.g. hydrocarbons and
alcohols, is also discussed.
Liverpool
December 1 9 79
C.H. Bamford
C.F.H. Tipper

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